Long-term transport behavior of psychoactive compounds in sewage-affected groundwater

Thi Nham, H.T. and Greskowiak , J. and Hamann, E. and Meffe, R. and Hass, U. and Massmann, G. (2016) Long-term transport behavior of psychoactive compounds in sewage-affected groundwater. Grundwasser, 21 (4). pp. 321-332. ISSN 1430-483X

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Official URL: http://dx.doi.org/10.1007/s00767-016-0336-x

Abstract

The present study provides a model-based characterization of the long-term transport behavior of five psychoactive compounds (meprobamate, pyrithyldione, primidone, phenobarbital and phenylethylmalonamide) introduced into groundwater via sewage irrigation in Berlin, Germany. Compounds are still present in the groundwater despite the sewage farm closure in the year 1980. Due to the limited information on (i) compound concentrations in the source water and (ii) substance properties, a total of 180 cross-sectional model realizations for each compound were carried out, covering a large range of possible parameter combinations. Results were compared with the present-day contamination patterns in the aquifer and the most likely scenarios were identified based on a number of model performance criteria. The simulation results show that (i) compounds are highly persistent under the present field conditions, and (ii) sorption is insignificant. Thus, back-diffusion from low permeability zones appears as the main reason for the compound retardation.

Item Type: Article
Uncontrolled Keywords: Sewage farm; Long-term groundwater pollution; Psychoactive drugs; Transport behaviour; Field scale reactive transport modelling
Subjects: G Geography. Anthropology. Recreation > GE Environmental Sciences
Depositing User: Dra. Raffaella Meffe
Date Deposited: 11 Oct 2016 08:04
Last Modified: 22 Nov 2016 15:53
URI: http://eprints.imdea-agua.org:13000/id/eprint/643

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