Rosal, R. and Rodríguez, A. and Perdigón-Melón, J.A. and Petre, A. and García-Calvo, E. and Gómez, M.J. and Agüera, A. and Fernández-Alba, A.R. (2009) Degradation of caffeine and identification of the transformation products generated by ozonation. Chemosphere, 74 (6). pp. 825-831. ISSN 00456535
Full text not available from this repository.Abstract
The ozonation of caffeine in water was performed at different pH values, including acidic conditions. Kinetic experiments were conducted by adding pulses of a concentrated caffeine solution to ozone saturated water. The results showed a rapid decrease of ozone concentration during the first 15 s after injection, followed by a gradual decline at a much slower rate. The data were fitted to a second order kinetic model with rate constants increasing from 0.25 to 1.05 M−1 s−1 for pH in the 3–10 range. The initial ozone consumption per mol of ozonated caffeine was greater at high pH values, reflecting a higher ozone decomposition rate. The decomposition of ozone was positively affected by the concentration of caffeine, an effect that could be attributed to the presence of a reaction intermediate from the ozonation of caffeine that behaved as a strong promoter of ozone decomposition. A study of the transformation products identified by liquid chromatography in combination with time-of-flight mass spectrometry was carried out, which permitted a tentative degradation pathway to be proposed and several persistent by-products to be identified at both pH 3 and 8. Most transformation products were the result of the opening of the imidazole ring after breaking caffeine’s N9C8 double bond.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Caffeine; Ozonation; Mineralization; Oxidation intermediates |
| Subjects: | T Technology > TD Environmental technology. Sanitary engineering T Technology > TP Chemical technology |
| Depositing User: | José Ángel Gómez Martín |
| Date Deposited: | 05 Jun 2013 14:58 |
| Last Modified: | 05 Jun 2013 14:58 |
| URI: | http://eprints.imdea-agua.org:13000/id/eprint/267 |
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